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NON-POLAR SOLUTE - POLAR SOLVENT:
Non-polar Iodine is not very soluble in water. An intermolecular
bond between an induced dipole (I2) and a polar bond
in water is not very strong compared to the hydrogen bonds in
water. The water molecules would rather remain hydrogen bonded
to each other, then to allow an iodine molecule come between
them. The water molecules effectively "squeeze" out
the non-polar iodine. The intermolecular forces are not roughly
equal, therefore, the "unlike" substances are not soluble
in each other.
Various gases such as O2, N2, H2,
CO2 are not very soluble because the gases are essentially
non-polar. Of course you may say that oxygen must be dissolved
in water to sustain fish life -- true, but the solubility is
very low. Carbon dioxide is soluble in water such as carbonated
beverages -- again this is true but why does it fizz when opened
or lose the bubbles on standing? Carbon dioxide is not very soluble
in water.
Demonstrations with Solubility:
Flaming Wood Splint
Deep Purple Magic
Lava Lamp
Dancing Raisins
Micelles and Detergents
have many application of the solubility of polar and non-polar
substances.
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