Gold Processing  Elmhurst College
 Chemistry Department
   Virtual ChemBook

Spraying cyanide on leach padsat the Zortman-Landusky mine
in Montana (Credit: Timothy Green)

Heap Leaching: extraction of gold using heap leaching and carbon recovery

Conversion of Gold Ore to Gold Metal

Adapted from: PAMP (Produits Artistiques de Métaux Précieux), a gold, silver and platinum group metals refinery based at Castel San Pietro, in Switzerland
http://www.pamp.com/gold_c/Info_site/in_glos/in_
glos_heapleaching.html

Heap Leaching

The successful application of heap leaching to the extraction of gold from low-grade deposits has been one of the main factors in higher output since the 1970s, especially in the United States. It is a low cost process that extracts a soluble precious metal or copper compound by dissolving the metal content from the crushed ore.

Ore is heaped onto open-air leach pads with a base of asphalt or impervious plastic sheeting. A sprinkler system is then laid along the top of the ore pile through which a solution of dilute cyanide is sprayed. The cyanide percolates down through the heap for several weeks, leaching out the gold. This solution, now enriched with gold, drains off the bottom of the pad into what is known as the "pregnant pond", from which it is pumped to the recovery plant.

It should be noted that cyanide is extremely toxic and must be handled with special care.

Heap leaching of gold was pioneered in the United States in 1973 at Placer Development's Cortez open pit in Nevada and proved on a larger scale at Pegasus Gold's Zortman Landusky mine in Montana. Although it is low cost, recovery rates average only sixty to seventy per cent, significantly less than with conventional milling. But it has enabled low-grade ores, which otherwise might not be economically viable, to be processed. In the United States, where heap leaching is used most extensively, half of all production is won by this method.

Cyanide/Cyanidation
Cyanide ions have a natural affinity for gold, which reacts with the gold solid particles to make gold cyanide complexes which are soluble in water. Cyanidation has been the principal method of extracting gold from ore since the development of the MacArthur-Forrest Process in 1887, which proved crucial in the development of the South African gold mining industry.

The perfection of the cyanide process largely replaced amalgamation with mercury that had previously been the main method of extracting gold from ore. Cyanidation has also become crucial since 1970 in gold recovery from low grade deposits through heap leaching. It should be noted that cyanide is extremely toxic and must be handled with special care.

In the MacArthur Forrest Process the ore is crushed to a fine powder and circulated through tanks containing a weak solution of cyanide, which has form tetracyano gold complexes. The complexation reaction results in dissolving the gold and the remaining rock pulp is filtered off. Zinc dust added to the cyanide solution to chemically reduce the gold oxidation state from III to zero. The gold is now in the metal element state with zero charge and appears as fine specks of gold to be precipitated out and the precipitate is then refined.